Changchun PVB B-17HX

Polyvinyl butyral (PVB), due to its excellent transparency, toughness, superior metal adhesion, and good film-forming properties, occupies an important position in coatings, adhesives, printing inks, and safety glass interlayers. By adjusting the degree of polymerization (molecular weight), degree of acetalization, and residual hydroxyl content, PVB is endowed with diverse physicochemical properties, forming a matrix of specifications to meet different industrial needs.     1. Core Specification System: Performance Comparison of HX, SY, and TX Series The differences in PVB specifications are mainly reflected in two dimensions: viscosity (molecular weight) and degree of acetalization. 1.1 Differences in Viscosity (Molecular Weight) Grades Viscosity is a core indicator determining the processing fluidity and film strength of PVB. ♠ Low-viscosity grades (PVB Resin B-02HX, CCP B-03HX): Performance characteristics: Excellent dissolution speed and low viscosity at high solid content, with strong permeability. Key applications: Mainly used in printing inks, metal foil coatings, and penetrating primers. Due to its shorter molecular chains, it provides a smooth film surface and good wettability. ♠ Medium-viscosity grades (CCP B-06HX, Changchun PVB B-08HX): Performance characteristics: Balances processability and toughness, making it the most widely used "all-rounder" grade. Key applications: Widely used in wood coatings (sealers) and ceramic adhesives. Its viscosity is sufficient to maintain pigment suspension while ensuring the strength of the green body after sintering. ♠ High-viscosity grades (Changchun PVB B-17HX, PVB B-20HXB): Performance characteristics: High molecular weight, resulting in extremely high impact strength and tensile strength after film formation. Key applications: Primarily used in safety helmets/composite materials and peelable protective films. In these areas, PVB provides strong structural support, preventing materials from shattering under stress. 1.2 Trade-off between Degree of Acetalization and Polarity ♣ HX series (standard type): The degree of acetalization ranges from 72-88wt%, providing good general solubility (e.g., in alcohol solvents). ♣SY series (high degree of acetalization): This series has a higher butyral group content. Comparative Advantages: Increased acetal content means enhanced hydrophobicity. Compared to the HX series, the SY series exhibits superior solubility in non-polar solvents (such as methyl ethyl ketone and toluene mixtures), lower water absorption, and better dimensional stability. It is commonly used in special paints or precision electronic adhesives requiring excellent water resistance. ♣ TX Series (Special Modification): Comparative Advantages: Designed for high-temperature processing environments. Its optimized residual hydroxyl group distribution significantly improves heat resistance after crosslinking with resins. Key Applications: Specifically used in printed circuit boards (PCB) and copper foil adhesives, capable of withstanding the high temperatures during the soldering process.   2. Comparison of Solubility Behavior in Different Solvent Systems The performance of PVB is highly dependent on the choice of solvent. The manual indicates that PVB is readily soluble in alcohols, ketones, and esters, but insoluble in pure hydrocarbons. Solvent Strength Comparison: Alcohols (such as ethanol and isopropanol) are the most commonly used solvents, providing stable viscosity; while adding a small amount of aromatic solvents (such as toluene and xylene) not only reduces costs but also effectively lowers system viscosity and improves coating efficiency. Effect of Water Content: PVB is extremely sensitive to water. The manual emphasizes that even a very small amount of water in the solvent can lead to a sharp increase in solution viscosity, or even gelation. Therefore, in safety glass or optical films requiring high transparency, the solvent specifications must be strictly controlled.   3. Comparison of PVB's Functional Roles in Multiple Fields Adhesion vs. Sintering Residue (Ceramic Industry) In ceramic adhesives, compared to other organic resins, PVB's advantage lies in its extremely high green strength. It allows the powder to be tightly packed in the mold and has a "residue-free" characteristic during the sintering process, ensuring the electrical performance and mechanical structure of the ceramic product. Anti-corrosion Function vs. Decorative Function (Metal Coating) In wash primers, PVB reacts with chromates and phosphates to form a chemically bonded layer on the metal surface, providing excellent anti-corrosion performance. This contrasts sharply with its role as purely a leveling agent and film-forming agent in baked enamel coatings for metal cans. Enhanced Toughness (Resin Modification) When PVB is used in combination with epoxy resin or phenolic resin, its function shifts from being the "main film-forming component" to a "modifier." Compared to the brittleness of pure epoxy resin, the addition of PVB significantly improves impact toughness and adhesion to metals due to the incorporation of long-chain PVB into the cross-linked network formed during the resin curing process.   Low-viscosity grades prioritize flow and penetration, making them ideal for inks and primers; High-viscosity grades prioritize strength and toughness, making them core components for structural materials and protective films; High acetal content and modified grades (SY/TX) provide specialized solutions for extreme environments requiring water and heat resistance.   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com

Since the late 1930s, polyvinyl butyral (PVB), a type of thermoplastic resin, has been key to making laminated glass. Laminated glass consists of one or more layers of PVB film (the interlayer) between two or more pieces of glass, bonded together using heat and pressure. This structure endows the finished glass with a range of unique properties, making it a crucial safety and functional material in the automotive industry and modern construction.   1. Chemical Basis and Unique Properties of PVB Resin 1.1 Structure and Synthesis PVB resin is a synthetic polymer obtained from polyvinyl alcohol (PVA) and butyral through an acetalization reaction. Its molecular chain contains three main functional groups: Butyral group: Responsible for providing the polymer with hydrophobicity, elasticity, and solubility. Hydroxy group: Maintains the polymer's strong adhesion to glass surfaces, heat resistance, and compatibility with plasticizers. Vinyl acetate group:，Usually present in small amounts, it has a fine-tuning effect on the glass transition temperature (Tg) and processing properties of PVB. This unique structure endows PVB with a range of ideal properties for laminated glass applications. 1.2 Key Physical Properties As the interlayer in laminated glass, PVB film must possess the following core physical properties: High Adhesion Strength: Strong adhesion to the glass surface ensures that glass fragments adhere firmly to the film upon impact. Excellent Elasticity and Toughness: Ability to absorb impact energy and effectively prevent penetration, forming the physical basis for the safety of laminated glass. Optical Transparency: Extremely high light transmittance in the visible light range, without affecting driver visibility or building lighting. Aging Resistance: Maintaining its mechanical and optical properties even under harsh environments such as ultraviolet radiation, humidity, and temperature variations.     2. Core Applications and Functions in Automotive Glass Automotive glass is one of the earliest and most important application markets for PVB resin. PVB plays a dual role in automotive windshields, providing both safety and functionality. CCP PVB B-18FS, combined with plasticizer 3GO and additives, can be extruded to produce various PVB interlayer films for architectural and automotive applications. 2.1 Collision Safety and Fragment Retention This is the most critical role of PVB in automotive applications. In a vehicle collision, the windshield shatters, but the PVB interlayer can: Prevent Penetration: The windshield is designed to take in impact energy. This stops things like stones from getting through the glass into the car. Plus, it keeps passengers inside the car and protects them from head injuries if they hit the glass. Fragment Retention: Firmly adhere to broken glass, preventing sharp fragments from flying and causing secondary injuries to passengers. 2.2 Noise Reduction and Sound Insulation Performance Modern cars need to be more comfortable to drive. PVB films, mostly those made in a specific way, are good at quieting high-frequency vibrations. This cuts down on wind and road noise. For instance, Changchun PVB B-17HX is made with certain plasticizers and a specific molecular weight to improve its damping abilities. It works very well for car side windows and sunroofs, where better sound insulation is needed.   3. Applications of PVB Resin in Architectural Glass Laminated glass is used in a lot of construction projects. You can find it in curtain walls, skylights, interior walls, and railings. The application of PVB resin must adapt to more stringent requirements for structural strength, durability, and climate change mitigation. 3.1 Structural Safety and Disaster Resistance The main function of laminated glass in architecture is to provide structural integrity and disaster resistance. Storm and Earthquake Resistance: In severe weather, like hurricanes, typhoons, or earthquakes, PVB laminated glass can still hold its structure even if it breaks. This helps keep people and property inside safe, because the glass doesn't collapse or fall apart. Theft and Explosion Protection: Thickened multi-layer PVB laminated glass (usually a composite structure of multiple layers of PVB and glass) has extremely high impact resistance. It can effectively resist the impact of blunt objects or gunshots and is widely used in high-security locations such as banks, jewelry stores, and museums. In the shock wave of an explosion, the PVB layer can absorb energy, preventing glass shards from injuring people. 3.2 Energy Saving, Environmental Protection, and Aesthetic Design Technological advancements in PVB films have also made them part of building energy-saving solutions. Solar Control PVB: PVB films containing special additives or dyes can regulate the transmittance and reflectance of sunlight, reducing heat entering the interior (lowering U-value and SC value), thereby reducing air conditioning energy consumption. Colors and Patterns: PVB films can be customized in a variety of colors and can even be embedded with patterns or textiles, providing architects with a wealth of facade design and aesthetic choices to meet the complex needs of modern architecture for light, privacy, and appearance. 3.3 Durability and Long-Term Performance Architectural glass must withstand decades of outdoor exposure. PVB resin possesses excellent durability: Aging Resistance: High-quality PVB films have good resistance to ultraviolet rays and moisture, ensuring that laminated glass will not yellow or delaminate during long-term use. Edge Sealing: The edge bonding strength between PVB and glass is key to preventing moisture and air penetration, which is essential for maintaining the transparency of laminated glass and preventing internal fogging.   As the automotive and construction industries increasingly demand higher standards of safety, environmental protection, and functionality, PVB resin technology is constantly evolving: ♦ Competition and Integration of Innovative Materials While PVB remains the mainstream material, new interlayer materials such as ionic polymers (e.g., SGP/Surlyn) are competing in applications requiring high structural strength and rigidity, particularly in high-rise buildings. The future trend may involve the composite use of PVB with other polymers to achieve a superior performance balance. ♦ Intelligentization and Integration Future automotive and architectural glass will be more intelligent, with PVB films serving as carriers for functional materials: Thermal Management and Electrical Heating: PVB layers can integrate micro-wires or transparent conductive materials for defogging, defrosting, or intelligent dimming of glass. Integrated Antennas and Sensors: Integrating vehicle antennas or various environmental sensors into the PVB film layer achieves high functional integration and aesthetic optimization. ♦ Sustainable Development Under environmental pressures, developing PVB resins synthesized from renewable resources or bio-based raw materials, and improving PVB recycling technologies, will be significant challenges and development directions for the industry.   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com