Vinyl acetate-ethylene copolymer emulsion

Film-forming agents are important adjuvants in pesticide seed coatings and are key functional ingredients in seed coatings. The inclusion of film-forming agents allows seed coatings to form a film on the seed surface, distinguishing them from other formulations such as dry powders, dispersible powders, liquids, and emulsions. The primary function of the film-forming agent in seed coatings is to adhere the active ingredient to the seed surface and form a uniform, smooth film. Film-forming agents need to be water-resistant to hold up in wet conditions like rice paddies, but they also need to let some water through so seeds can grow. It’s also good if they can soak up a bit of water from the soil, which helps seeds grow when it’s dry. Most polymers are good at one of these things, but not all. For example, it's hard to find something that’s both waterproof and lets water pass through. Right now, seed coatings often use just one polymer, so it’s tough to get all these properties at once. This is a main problem for making better seed coatings for rice fields.   Polyvinyl Alcohol (PVA), with its excellent film-forming, swelling, and water permeability, is currently the most widely used film-forming agent in seed coatings. However, its poor water resistance makes it susceptible to water erosion after seed coating, making it unsuitable for use alone in paddy fields or in high-humidity areas. VAE Emulsion (Vinyl Acetate–ethylene Copolymer Emulsion) exhibits strong water resistance, but VAE films only swell in water, not dissolve, and are impermeable to water. Clearly, VAE alone is also unsuitable as a seed coating agent. To address these issues, we used a solution blending method to prepare a series of blended films using PVA and VAE in varying ratios, hoping to improve the water resistance of Polyvinyl alcohol film (PVA film).     1. Microscopic Observation of the Blend System Figure 3-a shows that the PVA colloidal particles exhibit distinct micellar behavior, while the VAE colloidal particles exhibit relatively regular spherical shapes with particle sizes ranging from 700 to 900 nm and unclear outlines (Figure 3-b), consistent with literature reports. After blending, the outlines of the PVA and VAE colloidal particles clearly exhibit a core-shell structure (Figure 3-c), indicating that hydrogen bonding within the blend system alters the electron density around the particles. Furthermore, the particles of each phase are evenly distributed within the blend system, with no apparent interface formation, indicating good compatibility.     2. Water Resistance and Permeability of the Blend System The test results for the water permeability of the blend system are listed in Table 1. After the addition of PVA, the water permeability of VAE was significantly improved. The water permeabilities of vp10, vp20, vp30, and vp40 were ideal, meeting the requirements of seed germination and generally consistent with the results of the seed germination test. When we looked at how long it took for water to pass through, we found that as the VAE content went up, it took longer for water to start permeating: 0.2 hours (vp0), 0.25 hours (vp10), 0.5 hours (vp20), 0.75 hours (vp30), 1.2 hours (vp40), 2.5 hours (vp50), and over 6 hours (vp60-100). Except for vp0, all groups lasted the whole 24 hours without dissolving, which shows that adding VAE really made the material more water-resistant. The national standards GB 11175-89 and GB 15330-94 test water resistance and permeability by checking how much the film swells. These tests cannot fully capture the water permeation, water erosion, and subsequent dissolution of seed coating films used in this test. Visual assessment of these indicators is also difficult to accurately determine. The "L-shaped glass tube method" proposed in this paper measures the water permeability and water resistance of latex films. In principle, this method directly measures water permeation, water dissolution, and water solubility. Precise measuring instruments such as automatic samplers and pipettes are used for indicator control. Visual assessment of the "water permeation and dissolution" indicators and time measurements are easily determined. The experimental procedure is simple and can accurately reflect the actual performance of the membrane.     3. Effect of Modified Films on Seed Germination Rice seed germination tests (see Table 2) showed that blend films with less than 30% VAE didn't really change how well the seeds sprouted, so they should work fine for coating seeds. But, if the VAE is over 70%, the seeds didn't sprout well at all. None of the other samples sprouted well enough after 7 days to meet the standard.     Structural characterization of the blend films revealed good intermolecular compatibility between PVA and VAE after solution blending. The micelles in the PVA solution were opened, and no interface between the two phases was observed, demonstrating the feasibility of using VAE to modify PVA. The performance of PVA/VAE blend films at mass ratios of 80:20 and 70:30 was suitable for rice seed coating applications. Compared with PVA films alone, the introduction of VAE significantly improved the water resistance of the blend films, maintaining suitable water permeability and having no significant effect on seed germination. The method of modifying PVA blends with VAE emulsion is feasible for application in the film-forming agent field of pesticide seed coating agents.   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com

In the ever-changing construction industry, advances in materials science are crucial for promoting project quality, efficiency, and sustainability. From majestic skyscrapers to cozy homes, every structure relies on advanced building materials. Behind these materials lie hidden "unsung heroes" who play crucial roles at the microscopic level, ultimately determining a building's performance and longevity. Vinyl acetate-ethylene copolymer emulsion is one such indispensable and innovative material, its unique properties profoundly influencing the development of modern building materials.   1. What is VAE Emulsion? VAE emulsion is a polymer dispersion composed of a copolymer of vinyl acetate and ethylene. By varying the ratio of these two monomers, the emulsion's properties can be precisely tailored to meet diverse application requirements. In the construction industry, VAE emulsion is typically converted into a Re-Dispersible Emulsion (RDP Emulsion). This powder remains stable when dry, making it easy to store and transport. When added to water-based systems (such as cement-based mortars and gypsum-based putties), the VAE powder particles quickly absorb water and disperse, reforming into an emulsion. These redispersed emulsion droplets fuse during water evaporation, forming a continuous, elastic polymer film that firmly binds the inorganic particles (such as cement, gypsum, and fillers) in mortar or putty, providing additional performance enhancements. Property Contribution to Performance Flexibility Prevents cracking and improves longevity in dynamic applications Adhesion Forms strong bonds with inorganic materials, enhancing durability Water Resistance Ensures materials maintain integrity in moisture-prone areas Durability Enhances overall mechanical properties of construction materials   2. VAE emulsions give building materials "superpowers"   VAE emulsions (such as Vinnapas 400H) play such a crucial role in building materials due to their unique combination of excellent properties, which are highly compatible with cement-based materials:   2.1 Superior Adhesion This is one of VAE emulsions' most important contributions. While cement-based materials possess a certain degree of adhesion, they often struggle to adhere firmly to smooth, dense, or porous substrates. VAE emulsions can: Form a strong bond: During the drying process, the polymer chains of VAE emulsions penetrate the microscopic pores of the substrate and form a continuous, highly adhesive polymer film on the surface of the cement particles. Improved Bonding to Various Substrates: VAE-based materials bond well to a variety of building substrates, including concrete, mortar, gypsum board, wood, metal, and insulation boards, greatly expanding their application range. Improved Interfacial Strength: The introduction of VAE significantly enhances the bond strength at the material interface, making the connection between the mortar layer and the substrate, between different mortar layers, or between the mortar and finishing materials such as tiles more secure and reliable.   2.2 Enhanced Flexibility & Crack Resistance An inherent disadvantage of cement-based materials is their brittleness, which makes them prone to cracking when subjected to stress (such as temperature fluctuations, structural settlement, and vibration). VAE emulsions effectively address this issue: Introducing Flexibility: The incorporation of ethylene units into VAE copolymers imparts excellent flexibility to the polymer chains, resulting in a certain degree of ductility after drying and forming a film. Absorbing Stress: When the substrate undergoes slight deformation or temperature fluctuations that cause expansion and contraction, the flexible film formed by VAE absorbs and distributes these stresses, preventing the formation and propagation of cracks. Improved Impact Resistance: The presence of VAE also makes the material less susceptible to shattering upon impact, significantly enhancing its overall toughness.   2.3 Improved Water Resistance & Durability The continuous polymer film formed by VAE emulsions significantly improves the material's water resistance and overall durability: Waterproof Barrier: VAE films act as an effective waterproof barrier, reducing water penetration, protecting structures from moisture erosion, freeze-thaw cycles, and preventing rusting of internal steel reinforcement. Chemical Resistance: VAE polymers generally exhibit good resistance to a wide range of chemicals, enabling the material to maintain stable performance in a wider range of environments. Extended Service Life: By enhancing adhesion, crack resistance, and water resistance, VAE significantly extends the service life of building materials and reduces ongoing maintenance costs.   2.4 Excellent Film Formation & Cohesion The ability of VAE emulsions to form a continuous, uniform polymer film during the drying process is the foundation for the aforementioned properties: Particle Fusion: As water evaporates, the polymer particles in the VAE emulsion fuse from their dispersed state through forces such as van der Waals forces and hydrogen bonding, forming a dense, non-porous, continuous film. Improved. Cohesive Strength: The VAE film not only bonds to the external substrate but also acts as an internal "adhesive," holding together inorganic particles like cement and sand. This significantly enhances the cohesive strength of mortar or putty, preventing it from flaking or disintegrating.   2.5 Compatibility with Cementitious Systems VAE emulsions (especially RDP forms) are specifically designed to work synergistically with inorganic binders such as cement and gypsum. Excellent Dispersibility: VAE powder quickly and evenly redisperses in water, forming a stable emulsion. No Impact on Setting Time: Generally, the addition of VAE does not significantly shorten or prolong the setting time of cement, making construction operations more convenient. Synergy: The flexibility, adhesion, and water resistance provided by VAE complement the high strength and hardness of cement-based materials, creating a high-performance composite material.   2. 6 Environmental Benefits As people become increasingly concerned about health and the environment, the environmental advantages of VAE emulsions are becoming increasingly prominent: Low VOC emissions: VAE emulsions and products made from them typically have very low volatile organic compound (VOC) content. This not only helps improve indoor air quality and reduce harm to the human body, but also complies with increasingly stringent environmental regulations. Reduced material loss: VAE's improved material performance and durability mean less material loss and a longer lifespan, reducing resource consumption at the source.   3. Typical Applications of VAE Emulsions Due to these superior properties, VAE emulsions (and their RDP forms) are widely used in: Tile Adhesives: Their excellent bond strength ensures tiles remain in place; their excellent flexibility adapts to the thermal expansion and contraction of the substrate and tiles, preventing hollowing and cracking. Self-Leveling Compounds: They significantly improve the adhesion, flexibility, and crack resistance of mortars, ensuring a smooth and durable floor screed. Wall Putties/Skim Coats: Improve the adhesion and crack resistance of putty, making it easier to sand and creating a smooth, even wall surface. EIFS: Used to bond insulation boards and facing mortar, providing excellent bond strength, impact resistance, and weather resistance. Repair Mortars: Strengthen the bond between the repair material and the existing structure, improving the durability and crack resistance of the repair layer. Waterproofing Materials: Used in flexible waterproof coatings or mortars, providing excellent waterproofing performance and crack resistance.   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com

VAE emulsions are environmentally friendly products. Vinyl groups are embedded in the polyvinyl acetate molecular chain, giving the polymer emulsion a low film-forming temperature and excellent film-forming properties. They exhibit strong adhesion to difficult-to-adhere materials such as PET, PVC, PE, and PP. The polymer film produced is very water and weather resistant. It also holds up well to scrubbing and remains flexible even at low temperatures. The thickness of VAE emulsions is impacted by a number of things.    1. Effect of Solids Content on Viscosity We conducted extensive testing on the formulations and process conditions of VAE Emulsion DA-180L and VINNAPAS 400, respectively. The data in the following tables are derived from these tests. The relationship between solids content and viscosity is shown in Table 1. As shown in Table 1, higher solids content increases viscosity. This is because higher solids content increases the number of colloidal particles in the same emulsion mass, reduces the amount of aqueous phase, and increases the total surface area of the particles. This enhances interparticle interactions and resistance to motion, resulting in higher viscosity.   2. Effect of Protective Colloids on Viscosity In emulsion polymerization, protective colloids are often used as emulsion stabilizers to improve emulsifier stability and adjust viscosity. The emulsion stability of partially hydrolyzed PVA is also related to the distribution of acetyl groups on the polymer chain. A higher degree of blockiness in the acetyl group distribution results in greater surface activity, better emulsion stability, and smaller and more viscous emulsions. The higher the PVA degree of polymerization, the higher the viscosity of the polyvinyl alcohol aqueous solution before polymerization, and the higher the viscosity of the VAE. The higher the degree of alcoholysis of PVA, the lower the viscosity of the VAE. PVA's protective colloid ability increases with increasing degree of polymerization. Low-degree PVA forms coarser latex particles and has lower viscosity. An increase in the degree of polymerization improves both the protective and dispersing capabilities. To maintain the dispersion and protective properties of PVA during emulsion polymerization, while only adjusting the viscosity, the total amount of PVA is typically kept constant, with only the ratio between the two adjusted. With other conditions remaining unchanged, adding 4.54 kg of PVA Polyvinyl Alcohol 088-20 will increase the viscosity of each batch by 100 mPa·s. Table 2 lists the molecular weight and molecular weight distribution of high- and low-viscosity VAE emulsions. Table 2 shows that the low-viscosity emulsion has a higher molecular weight, coarser particles, and a wider particle size distribution than the high-viscosity emulsion, resulting in lower viscosity.   3. Effect of Initial Initiator on Viscosity The initiator has a main influence on the speed of polymerization. The more initiator is used, the faster the polymerization reaction is, and the reaction is difficult to control. After the polymerization conditions and the type of initiator are determined, the amount of initiator can be used to adjust the molecular weight of the polymer. The more initiator is used, the smaller the molecular weight of the polymer is, and the viscosity of the emulsion increases, and vice versa. Among them, the amount of initial initiator (ICAT) added has the greatest impact. These data clearly show that the more initial initiator is added, the higher the viscosity of the emulsion. This is because the more initial initiator is added, the more difficult the monomer is to react or the reaction rate is slow in the initial stage, and the resulting polymer has a smaller molecular weight, smaller particle size, and higher viscosity.   4. Conclusions (1) The higher the solid content of the emulsion, the greater the viscosity. (2) The higher the degree of polymerization of the protective colloid PVA, the greater the viscosity of the emulsion, and vice versa. (3) The viscosity of the emulsion when PVA is used as a protective colloid is higher than that when cellulose or surfactant is used as a protective colloid. (4) With the same degree of polymerization, the higher the degree of alcoholysis, the lower the viscosity of the emulsion. (5) The more initial initiator and total amount of initiator added, the higher the viscosity of the emulsion.   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com

  1.Glue for paper packaging and cardboard: efficient bonding, environmentally friendly and safe VAE adhesives suitable for cardboard packaging, film-sheet lamination, paper tube/honeycomb sponge molding, as well as envelope making and book binding. This product line has some great technical benefits. It offers strong bonding and good heat resistance for different materials, including engineering plastics like PET and PS. Plus, it cures quickly, which can help boost production efficiency. Its formula system combines diversity and safety. It not only meets the regulatory requirements of food contact materials, but also has excellent spraying suitability, ensuring stable and uniform sizing effects during high-speed production, while keeping the equipment clean and reducing maintenance frequency. Recommended products: VINNAPAS EP 706K, EP 707K; VINNAPAS EAF 67, EAF 68     2. Woodworking glue: high strength, low formaldehyde VAE adhesives are really flexible when it comes to wood processing. They are great for things like furniture, wood floors, plywood, and doors and windows.This adhesive has excellent water resistance and heat resistance, fast curing speed, and adopts innovative DPX technology to achieve a hardener-free formula. At the same time, the formaldehyde content is controlled below 5ppm, effectively solving the yellowing problem. Its excellent overall performance is particularly suitable for impregnated paper or PVC veneer. In addition, VAE adhesives can ensure that the surface of the product reaches a very high degree of flatness, and support the addition of medium to high proportions of PUD (polyurethane dispersion), providing professional and efficient bonding solutions for various wood processing needs. Recommended products: EP 706K, EP 707K, VINNAPAS EP 645     3. Textile laminating adhesive: strong and water-resistant, cost-optimized The application of VAE adhesives in the textile industry covers the efficient lamination of cloth and sponge, artificial leather and PVC veneer, providing a variety of product options, covering a wide range of needs from high viscosity to low viscosity, and can provide high solid content formulas. Its excellent water resistance and excellent wet peel strength ensure a strong and lasting bonding effect.Plus, they require less thickening agent, plasticizer, and solvent, which means you can save on costs. Most importantly, VAE has excellent compatibility with materials such as natural latex, acrylic emulsion, polyurethane emulsion and styrene-butadiene latex, making it more cost-effective in various applications. Recommended products: EP 706K, VINNAPAS EP 708, EP 645     4. Tobacco glue: high-speed production, ultra-low residue VAE emulsions are really useful in the tobacco industry, especially for various types of adhesives like cigarette glues (including overlapping, nozzle, and packaging glues) and special adhesives for fast packaging machines. One of their main benefits is that they have very low levels of formaldehyde (less than 15 ppm) and residual vinyl acetate (under 100 ppm), which meets strict health and safety rules. There’s a full range of formulas available, from low to high viscosity, and they offer options with high solid content to suit different production needs. Recommended products: VINNAPAS EP 710, VINNAPAS 756   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com

WACKER makes VINNAPAS VAE dispersions, which are polymer binders made from vinyl acetate-ethylene (VAE) copolymers. These binders help make many products work better and be more eco-friendly. WACKER is the top producer of VAE dispersions and redispersible polymer powders. You can find their products in lots of areas like coatings, tile adhesives, exterior thermal insulation systems, self-leveling screeds, interior plasters, paper coatings, and adhesives. What are VAE Copolymer Dispersions? These copolymers are created by mixing vinyl acetate, a hard monomer, with ethylene, a soft monomer, through emulsion polymerization. The ethylene adds flexibility to the VAE dispersions, so they don’t need extra plasticizers.   Great Rheological Properties VINNAPAS dispersions that use polyvinyl alcohol (PVOH) are easy to work with for many adhesive tasks, like paper and packaging (VINNAPAS 706 & VINNAPAS 710) . They’re good for different application methods too, such as roller and spray coating(VINNAPAS EP 705 A).   Reduced Migration The special makeup of the copolymer means that we don't need plasticizers or film-forming agents in products with VAE dispersions. This opens up many options for making low-migration adhesives.   Improved Workability Dispersions made with surfactants usually have better shear-thinning properties compared to those made with polyvinyl alcohol. This leads to better sticking to plastics, clearer films, more water resistance, and easier spraying, which makes it easier to work with floor adhesives. Plus, they can handle more fillers.   APEO Removal When making dispersions for adhesives, we don't need to use surfactants with APEOs (alkylphenol ethoxylates). So, VINNAPAS dispersions meet tougher environmental standards (such as VINNAPAS EP 7000).   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com

In the ever-evolving world of textile production, manufacturers are constantly seeking innovative solutions to enhance product quality and efficiency. Vinyl Acetate Ethylene (VAE) emulsion has emerged as a game-changer, replacing traditional binders in various applications. VAE emulsion, also known as Vinyl Acetate Ethylene Copolymer Emulsion, offers a significant advantage over traditional binders by enhancing the quality and durability of textile products. The unique properties of VAE emulsion enable better adhesion, improved flexibility, and superior resistance to environmental factors such as moisture and heat. This results in textiles that maintain their shape, color, and structural integrity throughout their lifecycle. VAE emulsion finds extensive use in the manufacturing of high-quality textile products. Its adhesive properties make it ideal for bonding various materials, including textiles, foams, and non-woven fabrics, without compromising softness or comfort. Whether it's for upholstery, automotive interiors, or apparel manufacturing, VAE emulsion provides excellent bonding strength and ensures impeccable product finish. With increasing demands for faster production cycles, VAE emulsion offers notable advantages in terms of efficiency and cost-effectiveness. Its VAE Re-Dispersible Emulsion form allows for easy application using conventional techniques, such as spray, brush, or roller. This reduces the production time, enhances productivity, and minimizes wastage. Furthermore, VAE emulsion eliminates the need for additional curing processes, reducing energy consumption and overall production costs. In line with the growing focus on sustainability, VAE emulsion demonstrates its environmental responsibility. Being water-based, it offers a greener alternative to solvent-based binders, minimizing the release of volatile organic compounds (VOCs) into the environment. VAE emulsion ( CW 40-707 & DA-500) is also free from hazardous substances, making it safe for both manufacturers and end-users.   Website: www.elephchem.com Whatsapp: (+)86 13851435272 E-mail: admin@elephchem.com   ElephChem Holding Limited, professional market expert in Polyvinyl Alcohol(PVA) and Vinyl Acetate–ethylene Copolymer Emulsion(VAE) with strong recognition and excellent plant facilities of international standards.

No, Ethylene Vinyl Acetate (EVA) is not the same as Vinyl Acetate-Ethylene (VAE,DA-310). While both EVA and VAE are copolymers of ethylene and vinyl acetate, they have different structures and properties.   EVA is a copolymer of ethylene and vinyl acetate, where the vinyl acetate content typically ranges from 5% to 50% by weight. It is a flexible, rubbery material commonly used in various applications such as footwear, packaging, and solar cell encapsulation due to its excellent flexibility, low-temperature toughness, and UV resistance. VAE, on the other hand, refers to a different type of copolymer formed by the polymerization of vinyl acetate and ethylene. In VAE, the vinyl acetate content is generally higher than in EVA, typically ranging from 10% to 60% by weight. VAE is often used as a binder or adhesive in construction materials such as paints, coatings, adhesives, and textiles.   So, while both EVA and VAE are copolymers of ethylene and vinyl acetate, they have different compositions and applications.

Proper storage of VAE Emulsion (Vinyl Acetate-Ethylene Copolymer Emulsion) is crucial to maintain its stability and performance over time. Here are some general guidelines for the storage of VAE Copolymer Emulsion:   1.Temperature and Environment: Store VAE emulsion in a cool, dry place. Avoid exposure to extreme temperatures and humidity, as these factors can impact the stability of Vinyl Acetate-Ethylene Copolymer Emulsion. Keep the storage area well-ventilated to prevent the buildup of heat and humidity.   2.Sealed Containers: Store ElephChem VAE emulsion in sealed containers to prevent water evaporation and contamination. Emulsions are water-based, and exposure to air can lead to changes in viscosity and other properties. Ensure that containers are tightly sealed after each use to minimize exposure to air.   3.Protection from Freezing: Protect ElephChem VAE emulsion from freezing. Freezing can lead to irreversible changes in the VAE emulsion's structure and result in a loss of performance. If the VAE emulsion has been exposed to freezing temperatures, it is advisable to thoroughly mix and test it before use.   4.Avoid Exposure to Sunlight: Shield VAE emulsion from direct sunlight. Ultraviolet (UV) radiation can potentially degrade the polymer and affect the performance of the emulsion.   5.Handling Precautions: Follow proper handling procedures to avoid contamination. Use clean equipment and tools when transferring or dispensing Vinyl Acetate-Ethylene Copolymer Emulsion. If possible, use a first-in, first-out (FIFO) system to ensure that older batches are used before newer ones.   6.Avoid Mixing with Incompatible Substances: Do not mix ElephChem VAE emulsion with incompatible substances. This includes avoiding contact with solvents or chemicals that may adversely affect Vinyl Acetate-Ethylene Copolymer Emulsion's stability.   7.Regular Inspection: Periodically inspect stored ElephChem VAE emulsion for any signs of separation, coagulation, or other abnormalities. If any issues are identified, investigate the cause and take corrective action as needed.   8.Manufacturer-ElephChem's Recommendations: Always refer to the specific recommendations provided by the manufacturer for the storage and handling of the particular ElephChem VAE copolymer emulsion you are using. Different formulations may have specific requirements. Following these storage guidelines helps ensure that ElephChem VAE Copolymer Emulsion (such as VAE DA-179)maintains its intended properties and performance throughout its shelf life. Always consult the product's technical data sheet or the manufacturer-ElephChem's guidelines for the most accurate and specific storage recommendations.